1,4-Dichlorobutane

• CAT Number: M067264
• CAS Number: 110-56-5
• Molecular Formula: C4H8Cl2
• Molecular Weight: 127.008
• Purity: ≥95%
• Synonyms: Tetramethylene chloride; 1,4-DICHLOROBUTANE
• Storage: -20°C
• IUPAC Name: 1,4-dichlorobutane
• InChI: InChI=1S/C4H8Cl2/c5-3-1-2-4-6/h1-4H2
• InChIKey: KJDRSWPQXHESDQ-UHFFFAOYSA-N
• SMILES: C(CCCl)CCl

1,4-Dichlorobutane (CAS 110-56-5), a colorless mobile liquid with a mild pleasant odor, is extensively used in the synthesis of a variety of ligands, including commonly used 1,1′-(1,4-butanediyl)bis(<wbr style="color: rgb(102, 94, 88); font-family: Arial, Helvetica, sans-serif; font-variant-ligatures: normal; orphans: 2; widows: 2;" />imidazole) (bbi), to prepare coordination polymers and metal-organic frameworks (MOFs). It can also be used a reagent in the synthesis of natural products such as spiro[4.5]-δ-damascone.

Reference

1.Ma, Jian-Fang, et al. "A porous supramolecular architecture from a copper (II) coordination polymer with a 3D four-connected 86 net." Inorganic chemistry 42.23 (2003): 7531-7534.
2.Ma, Jian-Fang, et al. "Four new coordination polymers of Cu (II) with 1, 1′-(1, 4-butanediyl) bis (imidazole)." Polyhedron 23.4 (2004): 553-559.
3.Liu, Ying-Ying, et al. "Structures of metal-organic networks based on flexible 1, 1′-(1, 4-butanediyl) bis (imidazole-2-phenyl) ligand." CrystEngComm 10.5 (2008): 565-572.
4.Lovchik, Martin A., and Philip Kraft. "Synthesis and Olfactory Properties of a 6′‐Silasubstituted “Spiro [4.5]‐δ‐Damascone”." Chemistry–A European Journal 23.19 (2017): 4590-4596.