4-​Chlorothiophenol(4-Chlorobenzenethiol)

• CAT Number: R017979
• CAS Number: 106-54-7
• Molecular Formula: C6H5ClS
• Molecular Weight: 144.616
• Purity: ≥95%
• Synonyms: 4-Chlorobenzenethiol; p-Chlorobenzenethiol; 1-Chloro-4-mercaptobenzene; 4-Chlorobenzenethiol; 4-Chlorophenylmercaptan; 4-Chlorophenylthiol; 4-Mercaptophenyl chloride; NSC 18714; NSC 229564; p-Chlorobenzenethiol; p-Chlorophenylmercaptan; p-Chloropheny
• Storage: -20°C
• IUPAC Name: 4-chlorobenzenethiol
• InChI: InChI=1S/C6H5ClS/c7-5-1-3-6(8)4-2-5/h1-4,8H
• InChIKey: VZXOZSQDJJNBRC-UHFFFAOYSA-N
• SMILES: C1=CC(=CC=C1S)Cl

4-​Chlorothiophenol(4-Chlorobenzenethiol) (CAS 106-54-7) undergoes oxidative coupling catalyzed by iron(III)-tetra phenyl prophyrin to form disulfides. 4-Chlorothiophenol was used to modify poly(vinyl chloride) and to synthesize poly(vinyl chloride) with halogen groups.

Reference

1.KARIMI, BAHADOR, et al. "Selective Oxidation of Thiols to Disulfides Catalyzed by Iron (III)–Tetra Phenyl Porphyrin Using Urea-Hydrogen Peroxide as Oxidizing Reagent." Turkish Journal of Chemistry 29.5 (2005): 539-546.
2.Navarro, Rodrigo, et al. "Modification of poly (vinyl chloride) with new aromatic thiol compounds. Synthesis and characterization." Polymer degradation and stability 93.3 (2008): 585-591.