4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE

• CAT Number: M035394
• CAS Number: 178265-65-1
• Molecular Formula: C21H16N4
• Molecular Weight: 324.387
• Purity: ≥95%
• Synonyms: 4-([2,2′:6′,2”-Terpyridin]-4′-yl)aniline; 4′-(4-aminophenyl)-2,2′:6′,2”-terpyridine; 4-(2,6-dipyridin-2-ylpyridin-4-yl)aniline
• Storage: -20°C
• IUPAC Name: 4-(2,6-dipyridin-2-ylpyridin-4-yl)aniline
• InChI: InChI=1S/C21H16N4/c22-17-9-7-15(8-10-17)16-13-20(18-5-1-3-11-23-18)25-21(14-16)19-6-2-4-12-24-19/h1-14H,22H2
• InChIKey: CYISWQZYBSHTNN-UHFFFAOYSA-N
• SMILES: C1=CC=NC(=C1)C2=CC(=CC(=N2)C3=CC=CC=N3)C4=CC=C(C=C4)N

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE (CAS 178265-65-1) is a tridentate oligopyridine ligand. Its crystalline structure has been investigated. It may be used as a ligand in the synthesis of terpyridine Ru(II) complexes, terpyridine based Cd(II) and Hg(II) complexes and heterobimetallic Ru(II)-Os(II) complexes.

Reference

1.Liu, H-G., Y-C. Qiu, and J-Z. Wu. "4′-(4-Methylphenyl)-2, 2′: 6′, 2′′-terpyridine." Acta Crystallographica Section E: Structure Reports Online 63.12 (2007): o4876-o4876.
2.Anthonysamy, Arockiam, et al. "Synthesis, characterization and electrochemistry of 4′-functionalized 2, 2′: 6′, 2 ″-terpyridine ruthenium (II) complexes and their biological activity." Dalton Transactions 16 (2008): 2136-2143.
3.Saghatforoush, Lotfali, Mehrdad Pourmohsen, and Parvin Asgari. "Synthesis, crystal structure and thermal properties of Cd (II) and Hg (II) terpyridine based compounds." Main Group Chemistry 13.1 (2014): 29-39. 
4.Maity, Dinesh, et al. "Photoinduced intramolecular energy transfer and anion sensing studies of isomeric Ru II Os II complexes derived from an asymmetric phenanthroline–terpyridine bridge." Dalton Transactions 43.4 (2014): 1829-1845.