Chlorodiethylaluminum

For research use only. Not for therapeutic Use.

  • CAT Number: I024583
  • CAS Number: 96-10-6
  • Molecular Formula: C4H10AlCl
  • Molecular Weight: 120.55
  • Purity: 98%
Inquiry Now

Chlorodiethylaluminum also know as Diethylaluminium chloride, it is a highly hazardous organic compound and Lewis acid with the chemical formula C4H10AlCl. When dissolved in hexane, diethylaluminum chloride is a colorless liquid. It is used for polyolefin catalysis and as an intermediate in the preparation of organometallic compounds. It has a vapor density of 4.2 (air=1)


Catalog Number I024583
CAS Number 96-10-6
Synonyms

Chlorodiethylaluminum; Aluminum, chlorodiethyl-; Chlorodiethylaluminum; Diethylaluminium chloride; Diethylchloroaluminum.

Molecular Formula C4H10AlCl
Purity 98%
Solubility Soluble in DMSO
Appearance Solid powder
Storage Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
IUPAC Name Aluminum, chlorodiethyl-
InChI InChI=1S/2C2H5.Al.ClH/c2*1-2;;/h2*1H2,2H3;;1H/q;;+1;/p-1
InChIKey YNLAOSYQHBDIKW-UHFFFAOYSA-M
SMILES CC[Al](Cl)CC
Reference

1: Huang C, Du S, Solan GA, Sun Y, Sun WH. From polyethylene waxes to HDPE using an α,α’-bis(arylimino)-2,3:5,6-bis(pentamethylene)pyridyl-chromium(iii) chloride pre-catalyst in ethylene polymerisation. Dalton Trans. 2017 May 30;46(21):6948-6957. doi: 10.1039/c7dt01077j. PubMed PMID: 28508901.
2: Alnajrani MN, Mair FS. Bidentate forms of β-triketimines: syntheses, characterization and outstanding performance of enamine-diimine cobalt complexes in isoprene polymerization. Dalton Trans. 2016 Jun 21;45(25):10435-46. doi: 10.1039/c6dt01064d. PubMed PMID: 27264840.
3: Ma J, Zhao KQ, Walton M, Wright JA, Hughes DL, Elsegood MR, Michiue K, Sun X, Redshaw C. Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability. Dalton Trans. 2014 Nov 28;43(44):16698-706. doi: 10.1039/c4dt01448k. PubMed PMID: 25271377.
4: Ma J, Zhao KQ, Walton MJ, Wright JA, Frese JW, Elsegood MR, Xing Q, Sun WH, Redshaw C. Vanadyl complexes bearing bi-dentate phenoxyimine ligands: synthesis, structural studies and ethylene polymerization capability. Dalton Trans. 2014 Jun 14;43(22):8300-10. doi: 10.1039/c4dt00021h. PubMed PMID: 24728221.
5: Yue E, Zhang L, Xing Q, Cao XP, Hao X, Redshaw C, Sun WH. 2-(1-(2-Benzhydrylnaphthylimino)ethyl)pyridylnickel halides: synthesis, characterization, and ethylene polymerization behavior. Dalton Trans. 2014 Jan 14;43(2):423-31. doi: 10.1039/c3dt52234b. Epub 2013 Oct 14. PubMed PMID: 24121649.
6: Hou X, Cai Z, Chen X, Wang L, Redshaw C, Sun WH. N-(5,6,7-trihydroquinolin-8-ylidene)-2-benzhydrylbenzenaminonickel halide complexes: synthesis, characterization and catalytic behavior towards ethylene polymerization. Dalton Trans. 2012 Feb 7;41(5):1617-23. doi: 10.1039/c1dt11766a. Epub 2011 Dec 8. PubMed PMID: 22159151.
7: Zhang W, Wang Y, Yu J, Redshaw C, Hao X, Sun WH. 2-(N-Alkylcarboxamide)-6-iminopyridyl palladium and nickel complexes: coordination chemistry and catalysis. Dalton Trans. 2011 Dec 28;40(48):12856-65. doi: 10.1039/c1dt11079a. Epub 2011 Oct 24. PubMed PMID: 22020535.
8: Yu J, Zeng Y, Huang W, Hao X, Sun WH. N-(5,6,7-Trihydroquinolin-8-ylidene)arylaminonickel dichlorides as highly active single-site pro-catalysts in ethylene polymerization. Dalton Trans. 2011 Sep 7;40(33):8436-43. doi: 10.1039/c1dt10541h. Epub 2011 Jul 21. PubMed PMID: 21779591.
9: Gao R, Xiao L, Hao X, Sun WH, Wang F. Synthesis of benzoxazolylpyridine nickel complexes and their efficient dimerization of ethylene to alpha-butene. Dalton Trans. 2008 Nov 7;(41):5645-51. doi: 10.1039/b807604a. Epub 2008 Sep 3. PubMed PMID: 18854903.

Request a Quote