For research use only. Not for therapeutic Use.
Gibberellin A4(CAS: 468-44-0) is a C19-gibberellin, initially identified in Gibberella fujikuroi and differing from gibberellin A1 by the substitution of the OH at C-7 (gibbane numbering) by H. It has a role as a plant metabolite. It is a lactone, a gibberellin monocarboxylic acid and a C19-gibberellin. It is a conjugate acid of a gibberellin A4(1-).
| Catalog Number | R015652 |
| CAS Number | 468-44-0 |
| Synonyms | 4a,1-(Epoxymethano)-7,9a-methanobenz[a]azulene, gibbane-1,10-dicarboxylic Acid Deriv.; GA4; 2β,4a-Dihydroxy-1-methyl-8-methylene-4aα,4bβ-gibbane-1α,10β-dicarboxylic Acid; (1α,2β,4aα,4bβ,10β)-2,4a-Dihydroxy-1-methyl-8-methylene-gibbane-1,10-dicarboxyl |
| Molecular Formula | C₁₉H₂₄O₅ |
| Purity | ≥95% |
| Target | Disease Research Fields |
| Storage | -20°C |
| IUPAC Name | (1R,2R,5R,8R,9S,10R,11S,12S)-12-hydroxy-11-methyl-6-methylidene-16-oxo-15-oxapentacyclo[9.3.2.15,8.01,10.02,8]heptadecane-9-carboxylic acid |
| InChI | InChI=1S/C19H24O5/c1-9-7-18-8-10(9)3-4-11(18)19-6-5-12(20)17(2,16(23)24-19)14(19)13(18)15(21)22/h10-14,20H,1,3-8H2,2H3,(H,21,22)/t10-,11-,12+,13-,14-,17-,18+,19-/m1/s1 |
| InChIKey | RSQSQJNRHICNNH-NFMPGMCNSA-N |
| SMILES | CC12C(CCC3(C1C(C45C3CCC(C4)C(=C)C5)C(=O)O)OC2=O)O |
| Reference | [1]: Sugai Y, Miyazaki S, Mukai S, Yumoto I, Natsume M, Kawaide H. Enzymatic total synthesis of gibberellin A₄ from acetate. Biosci Biotechnol Biochem. 2011;75(1):128-35. doi: 10.1271/bbb.100733. Epub 2011 Jan 7. PMID: 21228464.<br /> |
