Iron(III) Trifluoromethanesulfonate

• CAT Number: M005441
• CAS Number: 63295-48-7
• Molecular Formula: C3F9FeO9S3
• Molecular Weight: 503.035
• Purity: ≥95%
• Synonyms: Iron(III) trifluoromethanesulfonate;Iron 1,1,1-trifluoro-methanesulfonic acid;Iron(III) triflate;Iron(III) trifluoromethanesulfonate 90%;Iron(Ⅲ)trifluoroMethanesulfonate;Fe(CF3SO3)3;Fe(OTf)3;Ferric triflate
• Storage: Room temperature
• IUPAC Name: iron(3+);trifluoromethanesulfonate
• InChI: InChI=1S/3CHF3O3S.Fe/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
• InChIKey: OSHOQERNFGVVRH-UHFFFAOYSA-K
• SMILES: C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Fe+3]

Iron(III) Trifluoromethanesulfonate (CAS 63295-48-7) is one of numerous organometallic compounds. Iron(III) triflate is used as an efficient catalyst in the synthesis.

Reference

1.Zhou, Jiafen, et al. "FeCl3· 6H2O/C: an efficient and recyclable catalyst for the synthesis of 2, 3-unsaturated O-and S-glycosides." Journal of Carbohydrate Chemistry 33.6 (2014): 313-325.
2.Chen, Peiran, and Shaoshan Wang. "Iron (III) triflate, a new efficient catalyst for Type I Ferrier Rearrangement." Tetrahedron 68.27-28 (2012): 5356-5362.