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13637-68-8-Molybdenum dichloride dioxide Molybdenum dichloride dioxide

Molybdenum dichloride dioxide

For research use only. Not for therapeutic Use.

  • CAT Number: M058998
  • CAS Number: 13637-68-8
  • Molecular Formula: Cl2H2MoO2
  • Molecular Weight: 200.864
  • Purity: ≥95%
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Related Small Molecules: 4-Imidazolidinecarboxylicacid,2-oxo-,methylester,(S)-(9CI)     3-(4-Pyridyl)-L-alanine     2-Amino-4,6-dimethoxypyrimidine    

Molybdenum dichloride dioxide (Cat.No:M058998) is the inorganic compound with the formula MoO2Cl2. It is a yellow solid that is used as a precursor to other molybdenum compounds. It is a nonmolecular solid but is often encountered as its adducts MoO2Cl2(ether)2, which are soluble in organic solvents. It is one of several oxychlorides of molybdenum.


Catalog Number M058998
CAS Number 13637-68-8
Synonyms

MoO2Cl2

Molecular Formula Cl2H2MoO2
Purity ≥95%
Storage Store at -20°C
IUPAC Name dioxomolybdenum;dihydrochloride
InChI InChI=1S/2ClH.Mo.2O/h2*1H;;;
InChIKey ASLHVQCNFUOEEN-UHFFFAOYSA-N
SMILES O=[Mo]=O.Cl.Cl
Reference

[1]. Molecules. 2017 Feb 21;22(2):333. doi: 10.3390/molecules22020333.<br />
One-Pot Conversion of Epoxidized Soybean Oil (ESO) into Soy-Based Polyurethanes by MoCl₂O₂ Catalysis.<br />
Pantone V(1), Annese C(2), Fusco C(3), Fini P(4), Nacci A(5)(6), Russo A(7), D&#39;Accolti L(8)(9).<br />
Author information: (1)Greenswitch s.r.l., 75013 Ferrandina (MT), Italy. [email protected]. (2)ICCOM-CNR, SS Bari, Via Orabona 4, 70126 Bari, Italy. [email protected]. (3)ICCOM-CNR, SS Bari, Via Orabona 4, 70126 Bari, Italy. [email protected]. (4)IPCF-CNR, SS Bari, via E. Orabona 4, 70125 Bari, Italy. [email protected]. (5)ICCOM-CNR, SS Bari, Via Orabona 4, 70126 Bari, Italy. [email protected]. (6)Dipartimento di Chimica, Universit&agrave; di Bari &quot;A. Moro&quot;, Via Orabona 4, 70126 Bari, Italy. [email protected]. (7)Greenswitch s.r.l., 75013 Ferrandina (MT), Italy. [email protected]. (8)ICCOM-CNR, SS Bari, Via Orabona 4, 70126 Bari, Italy. [email protected]. (9)Dipartimento di Chimica, Universit&agrave; di Bari &quot;A. Moro&quot;, Via Orabona 4, 70126 Bari, Italy. [email protected].<br />
An innovative and eco-friendly one-pot synthesis of bio-based polyurethanes is proposed via the epoxy-ring opening of epoxidized soybean oil (ESO) with methanol, followed by the reaction of methoxy bio-polyols intermediates with 2,6-tolyl-diisocyanate (TDI). Both synthetic steps, methanolysis and polyurethane linkage formation, are promoted by a unique catalyst, molybdenum(VI) dichloride dioxide (MoCl₂O₂), which makes this procedure an efficient, cost-effective, and environmentally safer method amenable to industrial scale-up.<br />
DOI: 10.3390/molecules22020333 PMCID: PMC6155807 PMID: 28230803 [Indexed for MEDLINE]<br />
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[2]. Am J Clin Pathol. 1979 May;71(5):574-7. doi: 10.1093/ajcp/71.5.574.<br />
Cytochemical identification of tetrahydrofolate in human leukocytes.<br />
Kass L.<br />
Utilizing the ability of molybdenum dioxide dichloride to form a black insoluble precipitate with tetrahydrofolate, a cytochemical test for rapid detection of tetrahydrofolate in human leukocytes was developed. The test may be useful in distinguishing deficiency of vitamin B12 or folate or both from other disorders of erythropoiesis characterized by megaloblastic erythropoiesis.<br />
DOI: 10.1093/ajcp/71.5.574 PMID: 453075 [Indexed for MEDLINE]

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