N-PROPYLMAGNESIUM BROMIDE

• CAT Number: M007915
• CAS Number: 927-77-5
• Molecular Formula: C3H7BrMg
• Molecular Weight: 147.298
• Purity: ≥95%
• Synonyms: N-PROPYLMAGNESIUM BROMIDE;PROPYLMAGNESIUM BROMIDE;bromopropylmagnesium;n-Propylmagnesium Bromide 0.8 M In Tetrahydrofuran;27%intetrahydrofuranca.2mol/L;Magnesium, bromopropyl-;N-PROPYLMAGNESIUM BROMIDE: 27% (2M) IN TETRAHYDROFURAN;2MOL/L PROPYLMAGNES
• Storage: -20°C
• IUPAC Name: magnesium;propane;bromide
• InChI: InChI=1S/C3H7.BrH.Mg/c1-3-2;;/h1,3H2,2H3;1H;/q-1;;+2/p-1
• InChIKey: UGVPKMAWLOMPRS-UHFFFAOYSA-M
• SMILES: CC[CH2-].[Mg+2].[Br-]

N-PROPYLMAGNESIUM BROMIDE (CAS 927-77-5) is a useful chemical. It was used as precursor in the synthesis of octa-2,7-dienyl-magnesium bromide. It was also used in cross-coupling reactions. 

Reference

1.Felkin, Hugh, et al. "Nickel complex-catalysed reaction of propylmagnesium bromide with butadiene. A highly stereoselective synthesis of cis-and trans-(2-vinylcyclopentyl) methylmagnesium bromide." Journal of the Chemical Society, Chemical Communications 7 (1975): 242-243.
2.Terao, Jun, et al. "Ni-or Cu-catalyzed cross-coupling reaction of alkyl fluorides with Grignard reagents." Journal of the American Chemical Society 125.19 (2003): 5646-5647.